Ferrous sulfate heptahydrate

Ferrous sulfate heptahydrate

Tên sản phẩm Ferrous sulfate heptahydrate
Số CAS 7782-63-0
Các tên gọi khác Iron(II) sulfate heptahydrate; Green vitriol; Copperas
Công thức phân tử FeSO4·7H2O
Trọng lượng phân tử 278.01 g/mol
Hình thức Pale blue-green crystalline solid
Assay (FeSO4·7H2O) ≥ 99,01 TP3T
Iron Content 20.0–20.5%
Mất mát khi sấy khô ≤ 0,5%
Kim loại nặng ≤ 10 ppm
Độ hòa tan Soluble in water (25 g/100 mL at 20°C), insoluble in ethanol
Gói 25 kg net multi-wall paper bags with PE liner, or 1000 kg jumbo bags

Ferrous sulfate heptahydrate Structure

Synonyms: Ferrous sulfate heptahydrate, Iron(II) sulfate heptahydrate, Green vitriol, Copperas, Iron vitriol, FeSO4·7H2O, CAS 7782-63-0

Ferrous sulfate heptahydrate is the most common hydrated form of iron(II) sulfate, a pale blue-green crystalline solid that has been known since antiquity as green vitriol. It occurs naturally as the mineral melanterite and is produced on a large scale as a by-product of titanium dioxide manufacturing and steel pickling. The heptahydrate is the stable form under ambient conditions, containing seven molecules of water of crystallization. Historically, it served as a source of iron for ink making, water purification, and as a mordant in dyeing, roles that still find modern relevance.

Chemically, ferrous sulfate heptahydrate consists of Fe2+ ions coordinated with sulfate and water molecules. The iron is in the +2 oxidation state, which is essential for its bioavailability and reactivity. Upon heating, it loses water stepwise, turning white as the heptahydrate converts to the monohydrate and then anhydrous form. In aqueous solution, it readily oxidizes to ferric sulfate, especially in the presence of air, which is why stabilizers or acidic conditions are often employed. Its reducing properties make it valuable in various industrial and pharmaceutical applications.

In the pharmaceutical and nutraceutical industries, ferrous sulfate heptahydrate is a first-line iron supplement for the treatment and prevention of iron deficiency anemia. It is also used in water treatment as a coagulant, in agriculture as a soil amendment for iron chlorosis, and in the laboratory as a reducing agent and precursor for other iron compounds. The heptahydrate is preferred for many applications due to its high solubility and cost-effectiveness compared to other iron salts.

Ferrous sulfate heptahydrate is typically standardized to ≥99.0% purity, with iron content between 20.0% and 20.5%. It is available in various grades, including pharmaceutical grade (USP/BP/EP), food grade (FCC), and technical grade. The pharmaceutical grade is subject to strict limits on heavy metals and microbial contamination, ensuring safety for oral consumption. Its widespread availability and well-characterized properties make it a cornerstone in iron supplementation and industrial processes.

Chức năng

  • Iron supplementation: Provides bioavailable iron for the treatment and prevention of iron deficiency anemia.
  • Coagulant: Acts as a primary coagulant in water and wastewater treatment, removing phosphates and suspended solids.
  • Reducing agent: Used in chemical synthesis and as a reducing agent in laboratory and industrial processes.
  • Soil amendment: Corrects iron chlorosis in plants and improves soil conditions.
  • Mordant: Fixes dyes in textile dyeing and printing.
  • Nutritional fortification: Added to foods and feeds to enhance iron content.

Nguồn gốc và tiêu chuẩn hóa

  • Nguồn: Produced as a by-product of titanium dioxide production from ilmenite or as a primary product from steel pickling.
  • Production: Crystallization from aqueous solutions, followed by drying and purification.
  • Tiêu chuẩn hóa: ≥99.0% purity, with iron content 20.0–20.5%.
  • Forms: Pale blue-green crystals or powder.
  • Ứng dụng: Pharmaceuticals, water treatment, agriculture, food fortification, chemical synthesis.

Thông số kỹ thuật

Tham số Thông số kỹ thuật
Assay (FeSO4·7H2O) ≥ 99,01 TP3T
Xác định Positive for iron and sulfate
Mất mát khi sấy khô ≤ 0,5%
Kim loại nặng ≤ 10 ppm
Giới hạn vi sinh vật Total aerobic count ≤ 1000 cfu/g; Yeast & Mold ≤ 100 cfu/g; E. coli absent

Documentation & Supply

  • Công suất hàng tháng: 500 metric tons
  • Thời gian thực hiện: 3-5 business days (stock items)
  • Tài liệu hướng dẫn: COA, MSDS, TDS sẽ được cung cấp theo yêu cầu
  • Bao bì: 25 kg net multi-wall paper bags with PE liner, or 1000 kg jumbo bags

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