Ferrous sulfate heptahydrate

Ferrous sulfate heptahydrate

Nazwa produktu Ferrous sulfate heptahydrate
Numer CAS 7782-63-0
Inne nazwy Iron(II) sulfate heptahydrate; Green vitriol; Copperas
Wzór cząsteczkowy FeSO4·7H2O
Masa cząsteczkowa 278.01 g/mol
Wygląd Pale blue-green crystalline solid
Assay (FeSO4·7H2O) ≥ 99,01 TP3T
Iron Content 20.0–20.5%
Strata przy suszeniu ≤ 0,5%
Metale ciężkie ≤ 10 ppm
Rozpuszczalność Soluble in water (25 g/100 mL at 20°C), insoluble in ethanol
Opakowanie 25 kg net multi-wall paper bags with PE liner, or 1000 kg jumbo bags

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Ferrous sulfate heptahydrate Structure

Synonyms: Ferrous sulfate heptahydrate, Iron(II) sulfate heptahydrate, Green vitriol, Copperas, Iron vitriol, FeSO4·7H2O, CAS 7782-63-0

Ferrous sulfate heptahydrate is the most common hydrated form of iron(II) sulfate, a pale blue-green crystalline solid that has been known since antiquity as green vitriol. It occurs naturally as the mineral melanterite and is produced on a large scale as a by-product of titanium dioxide manufacturing and steel pickling. The heptahydrate is the stable form under ambient conditions, containing seven molecules of water of crystallization. Historically, it served as a source of iron for ink making, water purification, and as a mordant in dyeing, roles that still find modern relevance.

Chemically, ferrous sulfate heptahydrate consists of Fe2+ ions coordinated with sulfate and water molecules. The iron is in the +2 oxidation state, which is essential for its bioavailability and reactivity. Upon heating, it loses water stepwise, turning white as the heptahydrate converts to the monohydrate and then anhydrous form. In aqueous solution, it readily oxidizes to ferric sulfate, especially in the presence of air, which is why stabilizers or acidic conditions are often employed. Its reducing properties make it valuable in various industrial and pharmaceutical applications.

In the pharmaceutical and nutraceutical industries, ferrous sulfate heptahydrate is a first-line iron supplement for the treatment and prevention of iron deficiency anemia. It is also used in water treatment as a coagulant, in agriculture as a soil amendment for iron chlorosis, and in the laboratory as a reducing agent and precursor for other iron compounds. The heptahydrate is preferred for many applications due to its high solubility and cost-effectiveness compared to other iron salts.

Ferrous sulfate heptahydrate is typically standardized to ≥99.0% purity, with iron content between 20.0% and 20.5%. It is available in various grades, including pharmaceutical grade (USP/BP/EP), food grade (FCC), and technical grade. The pharmaceutical grade is subject to strict limits on heavy metals and microbial contamination, ensuring safety for oral consumption. Its widespread availability and well-characterized properties make it a cornerstone in iron supplementation and industrial processes.

Funkcja

  • Iron supplementation: Provides bioavailable iron for the treatment and prevention of iron deficiency anemia.
  • Coagulant: Acts as a primary coagulant in water and wastewater treatment, removing phosphates and suspended solids.
  • Reducing agent: Used in chemical synthesis and as a reducing agent in laboratory and industrial processes.
  • Soil amendment: Corrects iron chlorosis in plants and improves soil conditions.
  • Mordant: Fixes dyes in textile dyeing and printing.
  • Nutritional fortification: Added to foods and feeds to enhance iron content.

Source & Standardization

  • Źródło: Produced as a by-product of titanium dioxide production from ilmenite or as a primary product from steel pickling.
  • Production: Crystallization from aqueous solutions, followed by drying and purification.
  • Standardization: ≥99.0% purity, with iron content 20.0–20.5%.
  • Forms: Pale blue-green crystals or powder.
  • Zastosowania: Pharmaceuticals, water treatment, agriculture, food fortification, chemical synthesis.

Dane techniczne

Parametr Specyfikacja
Assay (FeSO4·7H2O) ≥ 99,01 TP3T
Identyfikacja Positive for iron and sulfate
Strata przy suszeniu ≤ 0,5%
Metale ciężkie ≤ 10 ppm
Wartości graniczne dla mikroorganizmów Total aerobic count ≤ 1000 cfu/g; Yeast & Mold ≤ 100 cfu/g; E. coli absent

Documentation & Supply

  • Miesięczna wydajność: 500 metric tons
  • Czas realizacji: 3–5 dni roboczych (towary dostępne w magazynie)
  • Dokumentacja: COA, MSDS, TDS available upon request
  • Opakowanie: 25 kg net multi-wall paper bags with PE liner, or 1000 kg jumbo bags

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